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Strong field ligands interact directly with the metal d-electrons and causes pairing of the electrons. The compound so formed is a low spin complex. A complex can be classified as high spin or low spin. Ligands that have a low field strength, and thus high spin, are listed first and. Oxidation states in transition-metal complexes containing radical ligands “. Indeed, over 118 fe(ii) or fe(iii) complexes, all but one of the strong-field n/x (x = c,. P, as) complexes exhibit low relative metal–ligand bond lengths. Strong-field ligand: ligand that will give complex ions with the minimum number of unpaired electrons. Low-spin complex: complex ion with a minimum. 2- as a strong field ligand. High spin and low spin complexes
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Low spin d4 d5 d6 d7. Low spin configurations strong field ligand weak field ligand. 4d & 5d always. (i) because in the presence of strong ligands, the crystal field splitting energy is more than the. If the pairing energy is less than the crystal field splitting energy delta. Complexes that contain central metal ions other than co3+. Ligands that form high-spin complexes are called weak-field ligands. Strong field ligands such as cn-:
(a) usually produce high spin complexes and small crystal field splittings. Nitrite is a strong-field ligand, so the complex will be low spin. The size of the magnetic moment of a system containing unpaired electrons is related
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